Fluid Properties Research Articles

Thermodynamic and transport properties of triangular-well fluids from molecular dynamics

Thermodynamic and transport properties of particles interacting via the triangular-well potential in the range of 1.4 ≤ λ ≤ 2.6 have been studied using perturbation theory and Molecular Dynamics simulations. We present thermodynamic properties such as vapour-liquid coexistence, vapour pressures, and density for different values of the attractive range potential. Good agreement is observed between the theoretical approach and computer simulations in a wide range of densities, temperatures, and pressures. Additionally, we show Molecular Dynamic simulation results of transport properties such as the self-diffusion coefficient as a function of both density and temperature. Finally, thermodynamic and transport properties of real fluids like oxygen, methane, hydrogen sulfide, and fluoromethane have been predicted using both approaches. Results of vapour-liquid coexistence, vapour pressures, and critical points were in excellent agreement with experimental data. The coupling of perturbation theory, Molecular Dynamics simulations, and the triangular-well pair potential offers a versatile and efficient method to explore various real fluid systems, which would include associating fluids, complex molecular liquids, and colloidal systems. This approach can advance our understanding of these systems using a simple approach and to contribute the development of more accurate and predictive models.

Simultaneous influence of contact angle, capillary number, and contraction ratio on droplet dynamics in hydrophobic microchannel

Abstract In droplet-based microfluidic systems, droplet motion and behavior largely depend on fluid properties, flow conditions, and microchannel geometry. This study presents a model to predict droplet dynamics within a contraction microchannel, considering various factors, such as contact angle (θ), capillary number (Ca), and contraction ratio (C), within defined ranges, through the employment of a three-dimensional numerical simulation method. Droplets may undergo trap, squeeze, or breakup as they traverse the contraction microchannel, contingent upon the aforementioned factors. The transition from trap to squeeze is determined by the critical value of Capillary number (〖Ca〗_I). Within the squeezed regime, the contact angle influences droplet deformation and velocity within the contraction microchannel. However, when capillary number (〖Ca〗_II) in contraction microchannel increases to a specific threshold corresponding to the contraction ratio, the droplet no longer in contact with the wall and becomes independent of the contact angle, a phenomenon referred to as detachment. Moreover, the contact angle's impact on the transition of droplets from squeeze to breakup is contingent upon the microchannel's contraction ratio. This study provides a comprehensive overview of droplet behavior within microfluidic systems, offering valuable insights for the optimization and design of microsystems.

The mechanism by which thermal coupling leads to an asymptotic maldistribution stability boundary for flow boiling in parallel channels

Phase change heat transfer processes are attractive for the efficient thermal management of advanced semiconductor devices, with flow boiling in parallel microchannel heat sinks being one promising solution. However, there are several implementation challenges associated with two-phase flow in parallel microchannels, particularly flow maldistribution, which can adversely affect performance and reliability. Two-phase flow models can be useful in predicting and understanding the instability mechanisms that leads to maldistribution, such that parametric performance trends and safe regions of operation can be identified. Channel-to-channel thermal coupling has been shown to alleviate maldistribution, but it is not yet understood why this effect is limited to some critical lateral thermal conductance above which there is no further benefit. In the current work, a two-phase flow model with a lumped thermal capacitance representation of the heat sink wall is developed to identify the mechanism for this asymptotic maldistribution stability boundary for thermally coupled microchannels. The lumped model allows the nature of stability boundary to be explained via a scaling analysis of the eigenvalues. In such systems, it is identified that a single eigenvalue determines the occurrence of flow maldistribution. Scaling analysis shows that, for small values of thermal conductance, this eigenvalue becomes a quadratic function of thermal coupling, which enhances the stability of microchannels and moves the stability boundary. However, for large values of thermal conductance, the eigenvalue is dependent only on the fluid properties, leading to a limit at which thermal coupling can no further improve stability or affect the stability boundary. The lumped model developed in this work enables mechanistic understanding of the role of channel-to-channel thermal coupling on mitigating flow maldistribution and therefore may offer important guidance on the design of flow boiling systems and heat sinks.

Development and Evaluation of a Novel Antibacterial Wound Dressing: A Powder Preparation Based on Cross-Linked Pullulan with Polyhexamethylene Biguanide for Hydrogel-Transition in Advanced Wound Management and Infection Control

As antibiotic resistance increasingly undermines traditional infection management strategies, there is a critical demand for innovative wound care solutions that address these emerging challenges. This study introduces a novel antibacterial wound dressing based on Cross-Linked Pullulan (Pul) and Polyhexamethylene Biguanide (PHMB) for enhanced wound management and infection control. The dressing’s adsorption rate reached 200% of its original weight within 30 min, exceeded 300% after 5 h, and exhibited significant non-Newtonian fluid properties. The dressings were able to release the loaded medication completely within 20 min; additionally, the dressing demonstrated significant antibacterial activity against a broad spectrum of bacteria. Significantly, the therapeutic effects of the Pul-PHMB/GP dressing were evaluated in a mouse model. Compared to untreated wounds, wounds treated with Pul-PHMB/GP exhibited a significant gelation process within 5 min post-treatment and showed a significant increase in wound healing rate within 12 days. This powder preparation overcomes the limitations associated with liquid and gel dressings, notably in storage and precise application, preventing the premature expansion or dissolution often caused by PHMB in high-humidity environments. The powder form can transform into a gel upon contact with wound exudate, ensuring accurate coverage of irregular wounds, such as those from burns or pressure sores, and offers excellent chemical and physical stability in a dry state, which facilitates storage and transport. This makes the dressing particularly suitable for emergency medical care and precision therapy, significantly improving the efficiency and adaptability of wound treatment and providing robust support for clinical treatments and emergency responses.

Levitation and dynamics of bodies in supersaturated fluids

A body immersed in a supersaturated fluid like carbonated water can accumulate a dynamic field of bubbles upon its surface. If the body is mobile, the attached bubbles can lift it upward against gravity, but a fluid-air interface can clean the surface of these lifting agents and the body may plummet. The process then begins anew, and continues for as long as the concentration of gas in the fluid supports it. In this work, experiments using fixed and free immersed bodies reveal fundamental features of force development and gas escape. A continuum model which incorporates the dynamics of a surface buoyancy field is used to predict the ranges of body mass and size, and fluid properties, for which the system is most dynamic, and those for which body excursions are suppressed. Simulations are then used to probe systems which are dominated by a small number of large bubbles. Body rotations at the surface are critical for driving periodic vertical motions of large bodies, which in turn can produce body wobbling, rolling, and damped surface ’bouncing’ dynamics.

Diffusing Wave Microrheology in Polymeric Fluids

Recently, there has been interest in determining the viscoelastic properties of polymeric liquids and other complex fluids by means of Diffusing Wave Spectroscopy (DWS). In this technique, light-scattering spectroscopy is applied to highly turbid fluids containing optical probe particles. The DWS spectrum is used to infer the time-dependent mean-square displacement and time-dependent diffusion coefficient D of the probes. From D, values for the storage modulus G′(ω) and the loss modulus G′′(ω) are obtained. This paper is primarily concerned with the inference of the mean-square displacement from a DWS spectrum. However, in much of the literature, central to the inference that is said to yield D is an invocation g(1)(t)=exp(−2q2X(t)2¯) of the Gaussian Approximation for the field correlation function g(1)(t) of the scattered light in terms of the mean-square displacement X(t)2¯ of a probe particle during time t. Experiment and simulation both show that the Gaussian approximation is invalid for probes in polymeric liquids and other complex fluids. In this paper, we obtain corrections to the Gaussian approximation that will assist in interpreting DWS spectra of probes in polymeric liquids. The corrections reveal that these DWS spectra receive contributions from higher moments X(t)2n¯, n>1, of the probe displacement distribution function.

Experimental Investigation of the Effects of Grooves in Fe2O4/Water Nanofluid Pool Boiling

In this study, we systematically explored how changing groove surfaces of iron oxide/water nanofluid could affect the pool boiling heat transfer. We aimed to investigate the effect of three types of grooves, namely rectangular, circular, and triangular, on the boiling heat transfer. The goal was to improve heat transfer performance by consciously changing surface structure. Comparative analyses were conducted with deionized water to provide valuable insights. Notably, the heat transfer coefficient (HTC) exhibited a significant increase in the presence of grooves. For deionized water, the HTC rose by 91.7% and 48.7% on circular and rectangular grooved surfaces, respectively. Surprisingly, the triangular-grooved surface showed a decrease of 32.9% in HTC compared to the flat surface. On the other hand, the performance of the nanofluid displayed intriguing trends. The HTC for the nanofluid diminished by 89.2% and 22.3% on rectangular and triangular grooved surfaces, while the circular-grooved surface exhibited a notable 41.2% increase in HTC. These results underscore the complex interplay between groove geometry, fluid properties, and heat transfer enhancement in nanofluid-based boiling. Hence, we thoroughly examine the underlying mechanisms and elements influencing these observed patterns in this research. The results provide important insights for further developments in this area by shedding light on how surface changes and groove geometry may greatly affect heat transfer in nanofluid-based pool boiling systems.

A new criterion for vanishing points of Widom lines of CO2/natural gas mixture: Application to pipeline and compressor units in CCUS

The Widom lines of mixture indicate the abnormal response behavior of properties of mixed supercritical fluid near the critical point, determining operating conditions in supercritical region of ground equipment in CCUS. Peng-Robinson equation (PR-EOS) is used to calculate Widom lines of isothermal compressibility coefficient, isobaric expansion coefficient, isobaric specific heat, and density of CO2/natural gas quinary mixture. A new criterion is proposed to calculate the vanishing points of Widom lines using the coefficient of variation (CV) of response function distribution, with a clear statistical meaning and an appropriate range, compared with existing criteria. Based on the new criterion, the effect of CO2 concentration on the thermodynamic fluctuations in the near-critical region of CO2/natural gas mixture is analyzed. It is found that thermodynamic fluctuations of mixture are controlled by CO2 concentration and fluctuations can be considered relatively weak when CO2 concentration is below 60 %. The selection and control of operating conditions of pipeline and compressor unit in CCUS application are discussed to cope with the Widom region movement caused by changes in CO2 concentration.

The Problem with NIST Thermodynamics Tables in Continuum Mechanics.

Thermodynamics is a fundamental topic of continuum mechanics and biomechanics, with a wide range of applications to physiological and biological processes. This study addresses two fundamental limitations of current thermodynamic treatments. First, thermodynamics tables distributed online by the U.S. National Institute of Standards and Technology report properties of fluids as a function of absolute temperature T and absolute pressure P. These properties include mass density ρ, specific internal energy u, enthalpy h=u+P/ρ and entropy s. However, formulations of jump conditions across phase boundaries derived from Newton's second law of motion and the first law of thermodynamics employ the gauge pressure p=P-Pr, where Pr is an arbitrarily selected referential absolute pressure. Interchanging p with P is not innocuous as it alters tabulated NIST values for u, while keeping h and s unchanged. Using p for functions of state and governing equations solves the problem with using NIST entries for the specific internal energy u in standard thermodynamics tables, and analyses of phase transformation in continuum mechanics. Second, constitutive models for the free energy of fluids, such as water and air, are not typically provided in standard thermodynamics treatments. This study proposes a set of constitutive models and validates them against suitably modified NIST data.

Mechanism and Study on Ball End Magnetorheological Fluid Finishing Process

The primary object of this research is to explore the capacities of BEMRF. Traditional polishing methods for glass commonly face challenges in reaching nanoscale precision and uniformity. In BEMRF, by controlling rheological properties of the MR fluid, we can tackle these challenges and potentially surpass the limitations of conventional techniques. The study includes the application of magnetorheological (MR) fluid with suspended magnetic particle abrasives to accomplish precision finishing by the manipulation of magnetic fields.

Evaluating the maximum drilling length of horizontal geothermal wells utilizing temperature constraints

The geothermal industry faces a significant challenge in exploring and developing resources due to elevated temperatures in downhole environments. Successful drilling in high-temperature geothermal wells requires precise thermal management. This research assesses constraints on horizontal section length and temperature during geothermal horizontal well drilling, aiming to formulate effective wellbore temperature management guidelines.The study utilizes thermal resistance analysis to establish a tailored transient heat transfer model for high-temperature horizontal geothermal well drilling. Parameters such as circulation time, horizontal section length, flow rate, drilling fluid properties, formation thermal conductivity, and drill string thermal conductivity are thoroughly investigated. Treating input parameters as triangular distributions, Monte Carlo simulation techniques conduct sensitivity analysis. Tornado diagrams quantitatively determine key parameter impacts on bottom-hole temperature. The research introduces a procedural framework for geothermal well drilling, aiding engineers in swiftly identifying operational parameter combinations for effective wellbore temperature management. This workflow provides practical guidance for geothermal resource development, ensuring drilling safety in diverse conditions.

Investigating radiative heat transfer, varied wall thickness, and slip effects on Casson nanofluid flow over a stretched sheet with heat source

ABSTRACT Understanding the intricate interplay between variable fluid properties such as slip and thermal conductivity when flowing over porous surfaces is of utmost importance for a wide range of engineering applications. This investigation delves into this uncharted territory, connecting the analytical capabilities of HAM (Homotopy Analysis Method) to reveal captivating insights into the impact of these variables on the dynamics of Casson nanofluid flow. Besides, we documented the flow aspects which include thermal radiation, heat source, variable wall thickness and chemical reaction. We alter the partial differential flow-related conditions into nonlinear ordinary ones employing the similarity transformation approach. Then, using a popular semi-analytical technique known as the Homotopy Analysis Method (HAM), we were able to untangle them. This method yields to power series solutions to nonlinear differential equations. To illustrate the impact of the velocity, temperature and concentration profiles, parametric research has been done using tables and diagrams. In the limiting sense, the numerical results of our methodology are in great association with the outcomes of previous research. Finally, it is noted that higher values of the velocity slip parameter cause an enhancement in fluid velocity, while escalating values of the thermal slip parameter cause a decline in temperature distribution.

Similar Solutions for Changing Characteristics of Natural Convection Laminar Flow around a Vertical Rectangular Inclined Plane Surface

The study investigates laminar natural convection flow around a vertical rectangular inclined plane surface, specifically focusing on the effects of viscous and pressure stress work. Previous research primarily addressed these effects in two-dimensional natural convection flow scenarios, while this study extends the analysis to encompass three exterior situations, accounting for variations in fluid properties outside compressible boundary layers. Employing numerical methods, the study aims to predict essential flow parameters including Prandtl’s number (Pr), controlling parameter (C), and additional parameters (A, B, D, E, ∅). The investigation yields velocity profiles (F'(0), S'(0)), temperature profiles , skin frictions (F''(0), S''(0)), and heat transfer coefficients θ'(0). Numerical results are presented to illustrate the impact of different parameters on these flow characteristics. Additionally, tabulated data in Tables-2 and Tables-3 offer further insights into the predicted flow parameters and their variations under varying conditions.

A Comparative study of flow and C[sbnd]C heat flux over a magnetic field under the influence of nanomaterial and carbon nanotubes

The aim of this study is to investigate convective heat transfer on a flat surface in the presence of magneto-hydro-dynamic (MHD) flow. The analysis considers the Darcy-Forchheimer porosity medium in the flow. The study focuses on analyzing the heat transfer rate, incorporating joule heating and convective-conductive heat flux effects. The influence of varying fluid properties on the flow behavior is examined. The governing flow equations are initially expressed as partial differential equations (PDEs) and then transformed into ordinary differential equations (ODEs) using appropriate similarity transformations. The numerical method RKF-45 is employed to solve these ODEs. The results highlight the impact of different parameters in the model. It is observed that a higher Darcy parameter leads to a decrease in fluid velocity. Additionally, the performance of carbon nanotubes is superior compared to MoS2 nanoparticles in this study.

Dynamic seismic signatures in a fluid‐saturated porous periodically layered medium considering effects of intrinsic anisotropy

AbstractThe interlayer wave‐induced fluid flow is an important mechanism for seismic attenuation and dispersion, as well as frequency‐dependent anisotropy, in the fluid‐saturated porous layered medium. This mechanism is closely related to the medium physical properties, and thus quantifying this mechanism is of significance for the seismic inversion of medium physical properties. Although numerous models have been proposed to quantify this mechanism, most models do not consider the effects of layer intrinsic anisotropy. To solve this problem, the effective complex‐valued and frequency‐dependent stiffness coefficients are derived for the fluid‐saturated porous medium composed of periodic transversely isotropic layers. Using the derived solutions, we study the effects of layer intrinsic anisotropy on seismic dispersion and attenuation, as well as frequency‐dependent anisotropy. It has been found that different matrix or fluid property contrasts between adjacent layers lead to different effects of intrinsic anisotropy. In addition, the effects of intrinsic anisotropy are also influenced by the fluid distribution when both matrix and fluid properties contrast among adjacent layers exist. In the low‐ and high‐frequency limits of wave‐induced fluid flow, our model reduces to the previous known results, which validates the correctness of our model. Our model can be applied in the seismic inversion of physical properties of reservoirs with intrinsic anisotropy, such as shale and tight sandstone reservoirs. In addition, our model can also be extended to cases with more complex intrinsic anisotropy and, thus, can be applied to complex anisotropic fractured reservoirs in the future.

What Rayleigh numbers are achievable under Oberbeck–Boussinesq conditions?

The validity of the Oberbeck–Boussinesq (OB) approximation in Rayleigh–Bénard (RB) convection is studied using the Gray & Giorgini (Intl J. Heat Mass Transfer, vol. 19, 1976, pp. 545–551) criterion that requires that the residuals, i.e. the terms that distinguish the full governing equations from their OB approximations, are kept below a certain small threshold $\hat {\sigma }$ . This gives constraints on the temperature and pressure variations of the fluid properties (density, absolute viscosity, specific heat at constant pressure $c_p$ , thermal expansion coefficient and thermal conductivity) and on the magnitudes of the pressure work and viscous dissipation terms in the heat equation, which all can be formulated as bounds regarding the maximum temperature difference in the system, $\varDelta$ , and the container height, $L$ . Thus for any given fluid and $\hat {\sigma }$ , one can calculate the OB-validity region (in terms of $\varDelta$ and $L$ ) and also the maximum achievable Rayleigh number ${{Ra}}_{max,\hat {\sigma }}$ , and we did so for fluids water, air, helium and pressurized SF $_6$ at room temperature, and cryogenic helium, for $\hat {\sigma }=5\,\%$ , $10\,\%$ and $20\,\%$ . For the most popular fluids in high- ${{Ra}}$ RB measurements, which are cryogenic helium and pressurized SF $_6$ , we have identified the most critical residual, which is associated with the temperature dependence of $c_p$ . Our direct numerical simulations (DNS) showed, however, that even when the values of $c_p$ can differ almost twice within the convection cell, this feature alone cannot explain a sudden and strong enhancement in the heat transport in the system, compared with its OB analogue.

Geometric influence of width ratio and contraction ratio on droplet dynamics in microchannel using a 3D numerical simulation

AbstractMicrochannel geometry is an important factor in determining droplet dynamics in droplet‐based microfluidic systems, much like fluid properties and flow conditions. In this context, two important geometric parameters—the contraction ratio () and the width ratio ()—that are limited to particular value ranges are taken into consideration for evaluation. These parameters interact with the capillary number () and viscosity ratio () to affect different aspects of droplet migration and manipulation, such as trap and squeeze regimes. A theoretical model is proposed, and a three‐dimensional numerical simulation method is used in this work. This model predicts the change from trap to squeeze, which is caused by the interaction of the previously mentioned variables. Interestingly, an inverse correlation exists between the width ratio and the critical capillary number for this transition, which is determined as . Furthermore, the investigation explores the droplet elongation and velocity ratio during their passage through the microchannel. By matching input parameters with microchannel geometry, this information may be useful for the design of microfluidic systems, which would facilitate the careful control and manipulation of droplets.

Numerical Approach for Investigating the Influence of Various Flow and Fluid Parameters on the Performance of a Cryogenic Two-Phase Flow Meter

Despite the intricacy, inline metering of two-phase flow has a significant impact in multitudinous applications, including nuclear fusion reactors, particle accelerators, and other systems that use cryogenic fluids. In this regard, a new concept for two-phase flow metering has been developed using model fluids. However, the geometric configurations of the channels and fluid properties are pivotal in ensuring accurate flow rate measurement. In this study, numerical analysis are performed to investigate the influence of channel width, number of channels, and gravitational field on the performance of the flow meter. The liquid height extracted from the volume fraction contour using an image processing tool has been used for calculating the mass flow rate of the liquid. The measured flow rate has been compared with the theoretical data, and it shows acceptable correspondence within ±6%. The investigations suggest that the increase in channel width governs the slope development. The appropriate width of the channel has been found to be ranging between 1mm and 3mm for the selected flow conditions and configurations. It is found that as the number of channels is increased from 10 to 20, the flow rate range that the system can measure within ±5% error has increased from 250g/s to 450g/s. The analysis broadened the reliability of the supposition and, therefore, provided a sturdy base for developing a cryogenic two-phase flow meter.

Effects of compressibility on Richtmyer–Meshkov instability of heavy/light interface

Experimental and numerical studies on the evolution of shock-accelerated SF6/air interface with small initial amplitude are conducted. The effect of compressibility on the early development of perturbation is highlighted by varying shock intensity and fluid properties. The startup process is analyzed when rarefaction waves are reflected and the characteristic time of the startup process is provided. The relationship between the phase inversion process and the startup process under different incident shock strengths is clarified. According to the startup time, a new start point for normalization is given, which can better normalize the amplitude growth at the early stage. In addition, the effects of incident shock strength and physical properties of fluids on the linear growth rate are highlighted through numerical simulations. The incompressible linear model loses validity when the incident shock is strong, and the existing rotational model is verified to provide excellent predictions under any shock strengths. The decrease in adiabatic exponent of the heavy fluid or the increase in adiabatic exponent of the light fluid can reduce the linear growth rate. As the absolute value of Atwood number increases, the adiabatic exponent of the heavy fluid has a more significant effect on the linear growth than that of the light fluid.

A unified fractional flow framework for predicting the liquid holdup in two-phase pipe flows

Two-phase pipe flow occurs frequently in oil & gas industry, nuclear power plants, and CCUS. Reliable calculations of gas void fraction (or liquid holdup) play a central role in two-phase pipe flow models. In this paper we apply the fractional flow theory to multiphase flow in pipes and present a unified modeling framework for predicting the fluid phase volume fractions over a broad range of pipe flow conditions. Compared to existing methods and correlations, this new framework provides a simple, approximate, and efficient way to estimate the phase volume fraction in two-phase pipe flow without invoking flow patterns. Notably, existing correlations for estimating phase volume fraction can be transformed and expressed under this modeling framework. Different fractional flow models are applicable to different flow conditions, and they demonstrate good agreement against experimental data within 5% errors when compared with an experimental database comprising of 2754 data groups from 14 literature sources, covering various pipe geometries, flow patterns, fluid properties and flow inclinations. The gas void fraction predicted by the framework developed in this work can be used as inputs to reliably model the hydraulic and thermal behaviors of two-phase pipe flows.